Polarization mode dispersion (PMD) is a property of a single-mode fiber or an optical component where pulse spreading is caused by different propagation velocities of the signal’s two orthogonal polarizations. Optical fibers or optical components can be modeled with two orthogonal polarization axes called principal states of polarization (PSP).
An optical signal propagating in a fiber is resolved into these two PSP axes. Each polarization axis (fast and slow axis) has a different propagation velocity. This is due to different refractive indexes in each axis caused by the birefringence of the material. The different velocities lead to pulse spreading at the receiver end.
PMD can be expressed as the square root of the fiber length multiplied by a proportionality coefficient. This coefficient is referred to as the PMD coefficient and is measured in units of picoseconds per square root kilometer (ps/√km). The PMD coefficient is typically specified by fiber cable manufacturers and represents the PMD characteristic for a particular length of that fiber.